Product ID:GASOLINES (ALL GRADES)
MSDS Date:08/24/1989
FSC:9130
NIIN:01-282-2844
MSDS Number: BKSYM

PHILLIPS CHEMICAL COMPANY

758 ADAMS BLDG
BARTLESVILLE, OK 74004
US

Emergency Phone: 918-661-3865/8118

Info Phone: 918-661-8327

Cage: FO153

PHILLIPS PETROLEUM CO

BARTLESVILLE, OK 74004 US

Telephone: 800-234-6603

Cage: 46935

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 100%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9192

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: <10%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: <2%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

P-XYLENE (P-DIMETHYLBENZENE) (SARA III)

CAS: 106-42-3

RTECS: ZE2625000

Fraction By Weight: <3%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

M-XYLENE (M-DIMETHYLBENZENE) (SARA III)

CAS: 108-38-3

RTECS: ZE2275000

Fraction By Weight: <6%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/15OSTEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

O-XYLENE (O-DIMETHYLBENZENE) (SARA III)

CAS: 95-47-6

RTECS: ZE2450000

Fraction By Weight: <3%

OSHA PEL 100PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: <15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: <3%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9192

TETRAETHYL LEAD (SARA III)

CAS: 78-00-2

RTECS: TP4550000

Fraction By Weight: <0.3%G/G

OSHA PEL S, 0.075MG/M3(PB)

ACGIH TLV: S, 0.1 MG/M3(PB)9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ANTIOXIDANT (5-15 POUNDS/1000 BARRELS)

Fraction By Weight: ABOVE

METAL DEACTIVATOR (1-3 POUNDS/1000 BARRELS)

Fraction By Weight: ABOVE

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: IRRITATION, CENTRAL NERVOUS
SYSTEM EFFECTS. GASOLINE IF SWALLOWED, MAY BE ASPIRATED INTO LUNGS,
RESULTING IN PULMONARY EDEMA AND CHEMICAL PNEUMONITIS. CHRONIC:
LEAD CAN CAUSE ILLNESS DUE TO EFF ECTS ON BLOOD, NERVES, KIDNEY AND
REPRODUCTIVE SYSTEM. BENZENE IS A CONFIRMED CARCINOGEN AND MAY
PRODUCE BLOOD CHANGES.
Explanation of Carcinogenicity:BENZENE IS A CONFIRMED CARCINOGEN BY
NTP, IARC AND OSHA.
Effects of Overexposure:EYES/SKIN: SLIGHT IRRITATION. INHALATION:
HEADACHE, NAUSEA, WEAKNESS, SEDATION, AND UNCONSCIOUSNESS.
INGESTION: IRRITATION TO INTESTINES. ASPIRATION INTO LUNG AFTER
INGESTION MAY RESULT IN PULMONARY E DEMA AND CHEMICAL PNEUMONITIS.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH A HISTORY OF SKIN
DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES.SEE DOCTOR.
SKIN: REMOVE CONTAMINATED CLOTHING AND SHOES. WASH WITH SOAP AND
WATER.SEE DOCTOR. INHALATION: REMOVE VICTIM TO FRESH AIR.GIVE
OXYGEN/CPR IF NEEDED.SEE DOCTOR. INGESTION: DO NOT INDUCE
VOMITING.SEE DOCTOR IMMEDIATELY. *** NOTE TO PHYSICIAN: GASTRIC
LAVAGE USING CUFFED ENDOTRACHEAL TUBE MAY BE PERFORMED AT YOUR
DISCRETION ***

Flash Point:<-35F,<-37C
Lower Limits:1.5
Upper Limits:7.6
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. VAPORS HEAVIER THAN
AIR.MAY TRAVEL ALONG GROUND AND FLASHBACK.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. VENTILATE AREA.
USE NON-SPARKING TOOLS. WEAR PROPER PROTECTIVE EQUIPMENT. STOP
LEAK.ABSORB IN INERT ABSORBENT AND PLACE INTO APPROPIATE DISPOSAL
CONTAINER AND SEAL. WASH AR EA WITH PLENTY OF WATER.

Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
PLACE,AWAY FROM HEAT,IGNITION SOURCES AND INCOMPATIBLE
MATERIALS.KEEP CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions:AVOID BREATHING VAPORS, AND EYE AND SKIN CONTACT. USE
ONLY WITH ADEQUATE VENTILATION. DO NOT SIPHON BY MOUTH. BOND AND
GROUND CONTAINERS DURING TRANSFER. PROTECT CONTAINERS FROM PHYSICAL
DAMAGE.

Respiratory Protection:NIOSH/MSHA RESPIRATOR WITH ORGANIC VAPOR
CARTRIDGE APPROPIATE FOR EXPOSURE OF CONCERN OR SCBA IF TLV IS
EXCEEDED.
Ventilation:SUFFICIENT MECHANICAL (GENERAL) AND/OR LOCAL EXHAUST
VENTILATION. USE EXPLOSION-PROOF EQUIPMENT.
Protective Gloves:VITON, NITRILE, PVA.
Eye Protection:SAFETY GLASSES WITH SIDE SHIELDS.
Other Protective Equipment:FULL BODY LONG-SLEEVED GARMENTS TO PREVENT
REPEATED OR PROLONGED SKIN CONTACT. EYE WASH STATION AND SAFETY
SHOWER.
Work Hygienic Practices:AVOID CONTACT WITH EYES AND SKIN. DO NOT
BREATHE VAPORS. WASH THOROUGHLY AFTER HANDLING. LAUNDER
CONTAMINATED CLOTHING.
Supplemental Safety and Health
THESE PRECAUTIONS ARE FOR NORMAL USES AND CONDITIONS. WHERE SPECIAL OR
UNUSUAL CONDITIONS EXIST, CONSULT AN INDUSTRIAL HYGIENIST. RCRA
CLASSIFICATION IGNITABLE (D001). EP TOXIC (D008).

HCC:F1
Boiling Pt:B.P. Text:80.0F,26.7C
Vapor Pres:350-800
Vapor Density:3-4
Spec Gravity:0.8
Evaporation Rate & Reference:>1 (BUTYL ACETATE = 1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:RED-ORANGE LIQUID. PUNGENT ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXYGEN AND STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:CARBON OXIDES, LEAD FUMES, AND VARIOUS
HYDROCARBONS WHEN BURNED.

Waste Disposal Methods:CONSULT YOUR LOCAL ENVIRONMENTAL OFFICER.
MANUFACTURER RECOMMENDS INCINERATION OR TRANSFER TO RCRA PERMITTED
WASTE MANAGEMENT FACILITY. DISPOSE OF IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.